总速率与正逆反应速率关系

pg电子官网ж¶ҲйҷӨйҖҹзҺҮеёёж•°(K)жҳҜжҢҮеҚ•дҪҚж—¶й—ҙеҶ…ж¶ҲйҷӨиҚҜзү©зҡ„еҲҶж•°гҖӮ7гҖҒиЎЁи§ӮеҲҶеёғе®№з§ҜиЎЁи§ӮеҲҶеёғе®№з§Ҝ(Vd)жҳҜжҢҮеҪ“иЎҖжөҶе’Ңз»„з»ҮеҶ…иҚҜзү©еҲҶеёғиҫҫеҲ°е№іиЎЎеҗҺ,дҪ“еҶ…иҚҜзү©жҢүжӯӨж—¶зҡ„иЎҖжөҶиҚҜзү©жө“еәҰеңЁдҪ“总速率pg电子官网与正逆反应速率关系(еҪұе“ҚжӯЈйҖҶеҸҚеә”йҖҹзҺҮзҡ„еӣ зҙ)1.иҶңеҸҚеә”жҖ§:жҢҮиҶңз”өдҪҚж°ҙе№іе’Ң0зӣёдёҠеҚҮжңҖеӨ§йҖҹзҺҮд№Ӣй—ҙзҡ„е…ізі»гҖӮеҸҚжҳдјеҜјйҖҹеәҰгҖӮ2.иҶңз”өдҪҚеӨ§,0зӣёдёҠеҚҮеҝ«,жҢҜе№…еӨ§,дјеҜјйҖҹеәҰе°ұеҝ«еӣӣгҖҒжңүж•ҲдёҚеә”жңҹ(ERP)1.д»ҺејҖе§ӢйҷӨжһҒиҮіиҶңз”өдҪҚжҒўеӨҚеҲ°вҖ“6050m

BгҖҒеңЁt2ж—¶еҲ»иӢҘжҳҜеҠе…ҘеӮ¬еҢ–еүӮ,з”ұдәҺеӮ¬еҢ–еүӮеҜ№жӯЈйҖҶеҸҚеә”йҖҹзҺҮйғҪжңүеҪұе“Қ,еӣҫиұЎдёӯйҖҶеҸҚеә”йҖҹзҺҮе’ҢжӯЈеҸҚеә”йҖҹзҺҮеҗҢзӯүзЁӢеәҰеўһеӨ§,иҖҢзҺ°еңЁйҖҶеҸҚеә”йҖҹзҺҮе…ҲеўһеӨ§жңҖеҗҺе’ҢеҺҹе№іиЎЎзӣёеҗҢ,йҖҹзҺҮдёҚеҸҳ,жңҖеҗҺеҸҚеә”иҫҫеҲ°е№і

д»Ҙд№pg电子官网ій…ёе’ҢNADдёәеә•зү©,еңЁ340nmзӣ‘жөӢеҗёе…үеәҰеўһй«ҳйҖҹзҺҮдёәжӯЈеҗ‘еҸҚеә”,д»ҘLD-LиЎЁзӨә;д»Ҙдёҷй…®й…ёе’ҢNADHдёәеә•зү©,зӣ‘жөӢ340nmеҗёе…үеәҰдёӢйҷҚйҖҹзҺҮдёәйҖҶеҗ‘еҸҚеә”,д»ҘLD-PиЎЁзӨәгҖӮжӯЈйҖҶеҸҚеә”дёӨжі•зӣёжҜ”,LD-Lжі•зҡ„дё»иҰҒ

еҪұе“ҚжӯЈйҖҶеҸҚеә”йҖҹзҺҮзҡ„еӣ зҙ

жё©еәҰеҚҮй«ҳ,еҲҶеӯҗеҸҳеҫ—жӣҙжҙ»и·ғ,еҸҚеә”йҖҹзҺҮдёҖе®ҡжҳҜеҠеҝ«зҡ„,дҪҶе®һйҷ…дёҠжңүиҝҷдәӣжғ…еҶө:в‘жё©еәҰеҚҮй«ҳ,еҸҚеә”зү©еҸ‘з”ҹдәҶдёҖдәӣеүҜеҸҚеә”жҲ–иҮӘеҲҶи§Ј,еҜјиҮҙеҸҚеә”зү©еҮҸе°‘,еҜјиҮҙж•ҙдҪ“еҸҚеә”еҸҳж…ўгҖӮв‘Ўжё©еәҰ

иЎҖжё…дёӯиғҪдёҺзўұжҖ§иӢҰе‘ій…ёеҸҚеә”зҡ„зү©иҙЁиҝҳжңүиӣӢзҷҪиҙЁгҖҒи‘Ўиҗ„зі–гҖҒжҠ—еқҸиЎҖй…ёгҖҒдёҷй…®гҖҒОұ-й…®й…ёзӯүгҖӮиҝҷдәӣвҖңеҒҮиӮҢй…җвҖқзү©иҙЁйҖҡеёёеҜ№иӮҢй…җжөӢе®ҡдә§з”ҹжӯЈе№Іжү°гҖӮз”ұдәҺе®ғ们зҡ„еҸҚеә”йҖҹеәҰжҜ”иӮҢй…җж…ў

з”ұдәҺж”ҫзғӯеүҜеҸҚеә”йҮҠж”ҫеҮәеӨ§йҮҸзғӯйҮҸ,еӣжӯӨжё©еҚҮйҖҹзҺҮжҜ”第дәҢйҳ¶ж®өжӣҙеҝ«[41]гҖӮеҗҢж—¶,з”ұдәҺжӯЈжһҒжқҗж–ҷдә§з”ҹзҡ„ж°§ж°”дҪҝз”өи§Јж¶Іж°§еҢ–гҖҒд»ҘеҸҠеүҜеҸҚеә”еҜјиҮҙSEIиҶңеҸ‘з”ҹеҲҶи§Ј,з”өжұејҖе§Ӣиҝ…йҖҹиҶЁиғҖ

дёҺе…¶д»–йқһз”ҹзү©еӮ¬еҢ–еүӮзӣёдјј,й…¶йҖҡиҝҮйҷҚдҪҺеҢ–еӯҰеҸҚеә”зҡ„жҙ»еҢ–иғҪ(з”ЁEaжҲ–О”GиЎЁзӨә)жқҘеҠеҝ«еҸҚеә”йҖҹзҺҮ,еӨ§еӨҡж•°зҡ„й…¶еҸҜд»Ҙе°Ҷе…¶еӮ¬еҢ–зҡ„еҸҚеә”д№ӢйҖҹзҺҮжҸҗй«ҳдёҠзҷҫдёҮеҖҚ;дәӢе®һдёҠ,й…¶жҳҜжҸҗдҫӣеҸҰдёҖжқЎ

3.йӣ¶зә§еҸҚеә”йӣ¶зә§еҸҚеә”йЎҫеҗҚжҖқд№ү,еҸҚеә”йҖҹзҺҮдёҺзү©иҙЁзҡ„жө“еәҰж—е…і,еҸҚеә”еҲ°йҖҹзҺҮж–№зЁӢдёӯdx/dt=k0,з§ҜеҲҶеҫ—x=k0t,k0еҚ•дҪҚmol/L^⑴В·s^⑴,t1/2=a/2k0гҖӮ4.е°Ҹз»“иҝҷдәӣйҖҹзҺҮж–№зЁӢйғҪжҳҜз”ұ-dc/dt=kвҲҸcaiеҸҳжҚў总速率pg电子官网与正逆反应速率关系(еҪұе“ҚжӯЈйҖҶеҸҚеә”йҖҹзҺҮзҡ„еӣ зҙ)жң¬ж–pg电子官网ҮжҸҗеҮәдәҶдёҖз§Қи®Ўз®—иҚҜзү©еҗёж”¶йҖҹзҺҮеёёж•°k_aзҡ„з®Җдҫҝз®—жі•.иҜҘжі•еҲ©з”ЁиЎҖиҚҜжө“еәҰ-ж—¶й—ҙжӣІзәҝзҡ„зү№еҫҒеҖј(еі°еҖјcmarиҫҫеі°ж—¶t_mеҸҠиҪ¬жҠҳеҖјc_1)жқҘзӣҙжҺҘи®Ўз®—k_a.и®Ўз®—е…¬ејҸеҰӮдёӢ:ејҸдёӯKдёәиҚҜзү©ж¶ҲйҷӨйҖҹзҺҮ